Document Type

Thesis

Date of Degree Completion

Spring 2010

Degree Name

Bachelor of Science

Department

Chemistry

Committee Chair

Dr. Anthony Diaz, Department of Chemistry

Second Committee Member

Dr. Dion Rivera, Department of Chemistry

Third Committee Member

Dr. Audrey D. Huerta, Director Science Honors Research Program

Abstract

The optical properties of gadolinium and europium doped samples of yttrium borate were assessed to determine a quantitative value for the host-to-activator energy transfer efficiency under VUV excitation. Emission, excitation, and reflectance data were collected through VUV spectroscopy. A plot of the energy transfer versus europium concentration was used to illustrate the behavior of the system with increasing amounts of europium. a/B ratios for each gadolinium concentration were calculated from trends given by the inverse energy transfer plot. These values show that with an increase of gadolinium in the crystal lattice, the a/B ratio increases. This indicates that there is a higher electron mobility resulting from a greater quantity of e-h pairs locating a europium site compared to a killer site when there is gadolinium is incorporated into the lattice.

Comments

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