Document Type

Thesis

Date of Degree Completion

Winter 2014

Degree Name

Bachelor of Science

Committee Chair

Dr. Carey Gazis, Department of Geological Science

Second Committee Member

Dr. Anne Egger, Department of Geological Science

Third Committee Member

Dr. Audrey D. Huerta, Director Science Honors Research Program

Abstract

Public outcry in early 2008 spurred recent studies to determine the concentration and source of nitrates in the Lower Yakima Valley groundwater. One study, conducted by the Environmental Protection Agency (EPA), used a variety of geochemical techniques to determine the source of these nitrates, which are likely from one or more of the following: dairy waste lagoons, fertilizers, septic systems, and other agricultural processes. In the study, they found that nitrate in a few groundwater samples had an isotopic signature that suggested an atmospheric source of nitrate. An atmospheric source is not common in terrestrial settings, but the most likely contributors are anthropogenic activities and direct deposition. Direct deposition may occur as NO3 gas interacts with surface soils and waters and in arid environments is incorporated into a soil precipitate, such as caliche. In this research, isotopic and major anion analyses were used to try to identify the source(s) of atmospheric nitrate found in the EPA study. Caliche layers within soils, in particular, were targeted as a potential source.

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