Document Type

Thesis

Date of Degree Completion

Spring 2008

Degree Name

Bachelor of Science

Department

Chemistry

Committee Chair

Dr. Anthony Diaz

Second Committee Member

Dr. Dion Rivera

Third Committee Member

Dr. Andrew A. Piacsek, Science Honors Research Program

Abstract

This paper reports on the synthesis and VUV optical characterization ofSrY2O4 doped with Eu³+. SrY2O₄:Eu³+ was synthesized from Y2O₃, Eu2O₃, and SrCO₃, with 5% excess SrCO₃ by weight; the mixture was fired at 1050 °C for 12 hrs in air twice; phase pure product was confirmed with powder X-ray diffraction. Reflectance data on an undoped sample reveals a band gap of about 6.leV. Results indicate that Eu³ occupies two non-equivalent Y sites within theSrY2O₄ framework. Calculation of maximum transfer efficiency forSrY2O₄:Eu³+ resulted in 60% with 35% lost to non-radiative decay via surface states.

Comments

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